Calcium Sulphate – CaSO4

Introduction

Limestones are a natural source of calcium sulphate. Calcium sulphate is an inorganic compound consisting of  \(CaS{O_4}\) and similar hydrates. In the form of anhydrite, it is currently commonly used as a desiccant.

Plaster of Paris is a specific hydrate, and the existence of all the others is attributable to the presence of the mineral gypsum. All of them look like insoluble white particles in water.

It is estimated that the world produces about 127 million metric tonnes of natural gypsum each year. Ca is a metal, but several of its compounds also play essential roles in various sectors and are therefore manufactured on a massive scale.

What is Calcium Sulphate?

Calcium sulphate as well as its hydrates are calcium salts. It appears as white particles that are far less soluble in water. The 2 most frequent hydrates include plaster of Paris as well as gypsum. Plaster of Paris seems to be a calcium sulphate hemihydrate produced if gypsum has been heated to 393 K. Whenever heated above 393 K, it produces anhydrite, sometimes termed as “dead burnt plaster,” that reverts to gypsum while added to water. Calcium sulphate is indeed an anti-caking agent, dough developer and strengthener, flour handling agent, pH controller, thickener, as well as yeast food. It has become a fine, odourless and white-yellow powder. It is required in the building sector to make artificial ceilings, plasters, as well as in various other materials.

Structure of Calcium Sulphate

\(CaS{O_4}\) is composed of 1 atom of Ca, 1 atom of S , as well as 4 atoms of O. It is an ionic molecule consisting of 1 calcium cation as well as 1 sulphate anion. The Ca ion has a valency of +2, whereas the sulphate polyatomic ion has a valency of -2. As a byproduct, whenever they interact, the neutral compound \(CaS{O_4}\) is formed.

Hydrous and Anhydrous Forms of Calcium Sulphate

Plaster of Paris and Gypsum

Both gypsum and plaster of Paris appear to be hydrated forms of  \(CaS{O_4}\). These two hydrated forms of calcium sulphate are well-known due to their numerous applications in various fields, including medicine and building. Plaster of Paris looks like a white powder that contains gypsum once it’s been hydrated fromCaSO4 salt. C

alcium sulphate hemihydrate is the technical name for them (\(CaS{O_4}.12{H_2}O\)). It’s being used much like a plaster cast to keep shattered bones in place while they heal. Gypsum is heated to 373 K, where it transforms into the compound. Chemically speaking, gypsum would be recognised as calcium sulphate dihydrate. \(CaS{O_4}.2{H_2}O\) must be its molecular formula.

It can be used to cover walls, ceilings, and even decorative pieces for protection and aesthetic purposes. It is impossible to form it into different forms. Once water is added to the plaster of Paris, it becomes gypsum and hardens.

Gypsum Formula

Uses of Calcium Sulphate

  • It is most useful in making Plaster of Paris. Because it can be easily transformed into a paste by mixing it with water,  \(CaS{O_4}\) powder is particularly useful in this regard.
  • It’s a high-quality calcium source.
  • It finds widespread use in the building trades and mortar production.
  • It is used in instruments for surgery, castings, moulds, and models.
  • It can be found in soil conditioners and fertilisers.
  • As with alabaster, it can be carved into works of art
  • It is being put to use in a process meant to boost the hardness of brewing water.
  • It’s used in the production of Portland cement.
  • Cosmetics like foot lotions and shampoos include it.
  • The dental industry is the primary user.
  • Lead and arsenic, both of which contribute to water pollution, can be removed by using calcium sulphate. 
  • Bread would get its calcium from calcium sulphate, which would also be used to fortify wheat.

Summary

An inorganic form of calcium, calcium sulphate occurs widely in the environment. It is possible to find hydrates of calcium sulphate in the wild.  \(CaS{O_4}\) is an inorganic calcium molecule with this chemical formula. Its primary ingredients are the well-known hydrates, Plaster of Paris and gypsum. Water does not dissolve this fine, odourless, white-yellow powder.  \(CaS{O_4}\) is used to strengthen flour due to its high calcium concentration. It has many applications in industrial production.

Frequently Asked Questions

1. What is Portland cement?

Portland cement is a binding material that comes in the form of a finely crushed powder, usually grey in colour, and is created by burning and grinding a mixture of limestone and clay or limestone and shale.

2. Is calcium sulphate mined or manufactured?

Commercial calcium sulphate is obtained from naturally occurring gypsum that is extracted or mined.

3. What property of calcium sulphate makes it a good food preservative?

Calcium Sulphate Dihydrate acts as a natural antioxidant, extending the expiry life of food as well as drinks.

Plaster of Paris Formula, Baking Soda, Washing Soda

Introduction:

Gypsum powder is called Plaster of Paris which is white. Gypsum is very common in Paris, which is how it earned its name. Gypsum is commonly heated to a higher temperature to make plaster of Paris. This is a dry powder that is mixed with water and hardens. When drying, this becomes flexible. In the field of architecture, plaster of Paris is used in a variety of ways. A famous substance, found in gauze bandages and sculpture materials is called the plaster of Paris.

Components of Plaster of Paris

Gypsum that has been roasted and milled into a fine powder is called plaster of Paris. Chemically it is written as\(\;CaS{O_4}.{\rm{ }}\raise.5ex\hbox{$\scriptstyle 1$}\kern-.1em/\kern-.15em\lower.25ex\hbox{$\scriptstyle 2$} {H_2}O\). Heat is generated as calcium sulfate transforms from its more soluble form\((CaS{O_4}.{\rm{ }}\raise.5ex\hbox{$\scriptstyle 1$}\kern-.1em/\kern-.15em\lower.25ex\hbox{$\scriptstyle 2$} {H_2}O)\) to its comparatively insoluble state\((CaS{O_4}.{\rm{ }}2{H_2}O)\) when water is added.

Properties of Plaster of Paris

  1. POP is an ideal material for forming moulds because it doesn’t stretch or break when dried. Beautiful plasterworks, including cornices, are frequently constructed and maintained with this technique.
  2. It is neither flammable nor combustible. It has a relatively weak chemical reactivity but, in extreme cases, can operate as an oxidizing agent. Hazardous sulfur oxides are produced during decomposition at moderately high temperatures. It creates gypsum \(CaS{O_4}\) by a slow and exothermic reaction with water or air moisture.
Plaster of Paris helps in setting the broken bones.

Washing Soda

Properties

A white, odorless dust is called washing soda. It has a chemical name termed sodium carbonate decahydrate, and its formula is\(\;N{a_2}C{O_3}.10{H_2}O\).

Its water-absorbing nature allows it to absorb moisture from the surrounding atmosphere. It is very soluble in water and creates a very basic solution.

Preparation

Through Solvay’s method, washing soda is produced. It starts as sodium bicarbonate, which is heated to become sodium carbonate. Finally, sodium carbonate is recrystallized to generate washing soda.

\[NaCl + N{H_3} + C{O_2} + {H_2}O{\rm{ }} \to {\rm{ }}NaHC{O_3} + N{H_4}Cl\]

\[2{\rm{ }}NaHC{O_3} \to N{a_2}C{O_3} + {H_2}O + C{O_2}\]

\[N{a_2}C{O_3} + 10{H_2}O \to {\rm{ }}N{a_2}C{O_3}.10{H_2}O\]

Baking Soda

Baking soda or bicarbonate of soda, also termed sodium bicarbonate,  is a chemical substance with the formula \(NaHC{O_3}\). Bicarbonate anion (\(HC{O_3}^ – \)) and the sodium cation (\(N{a^ + }\)) combine to form baking soda.

Properties

  1. A white crystalline substance with a density of around 2.2 g/mL is known as sodium hydrogen carbonate. It tastes alkaline and is only slightly soluble in water. With an increase in temperature, sodium hydrogen carbonate becomes more soluble.
  2. It is well known that baking soda can neutralize odors. Baking soda is therefore widely used to remove false odors from freezers and other closed spaces.

Preparation

In the reaction of a saturated sodium carbonate solution and carbon dioxide, sodium hydrogen carbonate (baking soda) is formed. Due to its low solubility, the white powder of sodium hydrogen carbonate isolates out.

Summary

Gypsum (calcium sulfate) powder and water are combined to create the plaster of Paris, which quickly dries. Medical professionals use plaster of paris to fix broken bones. Orthopedic casts still frequently utilize plaster of Paris. Washing soda’s pH is higher than that of baking soda. Baking soda, like the Arm & Hammer variety containing sodium bicarbonate, is edible and safe to use on human skin. It is not advisable to consume, breathe, or put alkaline washing soda on the skin.

Frequently Asked Question

1. How to make the plaster of Paris waterproof?

Ans: When the plaster of Paris is cured, it transforms into a highly porous material that will absorb any water that comes into contact with it. Plaster of Paris must have as many surface gaps as possible blocked to behave as waterproof for outdoors or brief exposure to water.

2. Is baking soda a blood pressure raiser?

Ans: Hypertension: Sodium bicarbonate may raise blood pressure. The use of sodium bicarbonate should be prohibited by individuals who already have high blood pressure. Low blood potassium levels: Sodium bicarbonate may decrease blood potassium levels.

3. What occurs if the plaster of Paris is left out in the open?

Ans: Plaster of Paris is a kind of rapid gypsum plaster that hardens when moistened and left to dry as it reacts with the moisture in the atmosphere to form gypsum. It is composed of a fine white powder termed calcium sulfate hemihydrate.