Tag: #Atomic structure

Introduction

An atom is the smallest unit of matter that preserves all the features of its element, while a molecule is a compound made up of numerous bonded atoms. Atoms and molecules are related, notwithstanding their differences. Atoms are the smallest unit of matter, while molecules are made up of several atoms, therefore they are clearly different from one another. A tomos, from the Greek a-tomos, means “indivisible,” which is apt because atoms are indivisible. Therefore, molecules can be further divided but atoms cannot.

Definition of Atom

Elements can be identified by their unique atoms, which are stable and resistant to chemical breakdown. Atoms typically consist of a nucleus composed of neutral protons and neutrons, with electrons carrying negative charges and circling the nucleus. The size of an atom is dependent on its number of protons and neutrons, as well as the existence or absence of electrons. The typical size of an atom is around 100 picometers, or 1/10 billionth of a metre. Nucleus mass is virtually entirely due to protons and neutrons because electrons contribute so little.

 Atomic Structure

Features of atom on the bases of modern atomic theory 

1. The term “modern atomic theory” is used to describe the most up-to-date, canonical explanation of atoms.
2. According to the foundations of atomic theory, atoms are the smallest units of chemical matter. They are the most basic building blocks of chemistry; they cannot be broken down any more.
3. Each element has its own distinct atomic structure, which differs from that of every other element.
4. Although, atoms can break down into much smaller particles. The nucleus of every element contains the same amount of protons, which are positively charged subatomic particles.
5. Neutrons are also present in the nucleus, albeit the exact number varies amongst isotopes of the same atomic type.
6. There are two types of atoms in the universe: isotopes, which have a varied number of neutrons but the same number of protons. For example, whereas all hydrogen atoms share a single proton, hydrogen-2 also has a neutron while hydrogen-1 does not.

 Proton, electron and neutron

Introduction of Molecule

Atoms of a molecule are held together in a certain configuration by chemical bonds. A molecule, like\({O_2}\), can consist of two or more atoms of the same element or of atoms from different elements. The properties of a chemical depend on the arrangements of its atoms within its molecule. The molecular weight is comparable to the sum of the atomic weights of the molecule’s constituent elements.

Bonding in Atoms

A molecule will be formed by bonding of two or more atoms. The atomic bonding is of several types such as:

Ionic bond

By sharing electrons between atoms, an ionic bond is formed. An ionically bonded substance is salt (NaCl), for instance. One of sodium’s outermost electrons is given up to chlorine so that the latter can finish filling its shell.

Covalent bond

To form a covalent bond, two or more atoms must share electrons from their outermost shell. Polymers are an example of materials that use covalent bonding. Polymers typically consist of long chains of hydrogen and carbon atoms connected via covalent bonds.

Metallic bond

When the electrons in the outermost shell are not paired with any particular atom or ion but instead exist as a “cloud” of electrons surrounding the ion centres, a metallic bond is formed. Magnesium, sodium, and aluminium are all examples of elements that form metallic bonds.

Difference between Atoms and Molecules

Summary

According to scientific consensus, the smallest unit of an element that can or cannot exist freely is an atom. Instead, the smallest unit of a compound is a molecule, which consists of a collection of atoms bound together by chemical forces. It’s possible for an atom to be either free or bound. To be sure, molecules exist in a liberated form as well. Aside from that, an atom has a nucleus filled with protons and neutrons and electrons around it. Conversely, molecules are made up of two or more atoms that are chemically bound together and may share some or all of their properties.

 

Frequently Asked Questions 

1. Are there no forces of attraction between the molecules of inert gases?

Ans. Inert gases have stable molecules that are not attracted to one another by electrostatic forces but do have weak van der Waals attractions and London dispersion forces.

2. Is  polar bond an ionic bond ?

Ans. No, a polar bond is not an ionic bond. It is a  specific kind of covalent bond which is formed between an electronegative and an electropositive atom .

3. What is the difference between positron and electron?

Ans. Electrons having the opposite chirality or quantum spin are called Positrons. The polarity of the electric charge is reversed since the spin is anticlockwise. Electrons are found inside an atom while positrons are not.

Introduction

Atomic orbitals are the three-dimensional spaces that surround the nucleus and are most likely to contain an electron. The atomic orbitals have been combined to create molecular orbitals. They obtain orbitals in quantum theory, some of which are electron shells in the s, p, d, and f configurations. Although orbitals come in a variety of shapes and sizes, their square can be used to estimate their size or even shape. A total of two, six, ten, or fourteen electrons could fit in the s, p, d, and f subshells, respectively. The particular arrangement of electrons within orbitals in such an atom determines the majority of the chemical compositions of that atom. Depending upon the energy over its electrons, every orbital class seems to have a distinct form. The s orbital has a spherical geometry. The p orbital has the form of a dumbbell, as well as 3p orbitals, which vary in their arrangement across a 3-dimensional axis.

Define Atomic Orbitals

Atomic orbitals are numerical values that provide additional details about the waveform of electrons that inevitably surround atom centers. In the fields of quantum systems and atomic theory, specific mathematical expressions are frequently employed to determine the likelihood of detecting an electron at even a specific area surrounding the nucleus of an atom. The term “atomic orbital” may also refer to the region above an atom’s nucleus where there is the greatest chance that a particular electron will become accessible. Several quantum numbers affect each atomic orbital’s characteristics:

Table of All Possible Atomic Orbitals, where the Value of ‘n’ Ranges from 0 to 5

What do you mean by Atomic Orbital Theory?

An atomic orbital is a statistical term that describes the location or even waveform behavior of such an electron in an atom in both atomic theory and quantum field theory. These electrons, each of which has a distinct spin quantum number s, can fit into any one of these orbitals up to a maximum of two. One such formula can be used to determine whether it is possible to find an electron inside the nucleus of any atom at any particular location.

Summary

Atomic orbitals seem to be the regions around the nucleus of an atom where electrons have often been observed at that particular time. This is a mathematical concept that characterizes the wave-like activity with 1-2 electrons in an atom. Electrons inhabit low-energy orbitals (near such nuclei) before electrons approach higher-energy orbitals. When there is an option of equal-energy orbitals, then occupy the orbitals freely as feasible. That filling of orbitals on its own is termed Hund’s law when applicable. Atomic orbitals are typically denoted by a series of digits as well as letters representing unique features of such electrons linked only with orbitals, including 1s, 2p, 3d, as well as 4f. Primary quantum numbers are values that further indicate levels of energy.

Frequently Asked Questions (FAQs)

1. Is it possible to have an orbital without an electron?

Ans. An orbital’s characteristics are more like the electron residing inside it. This is standard procedure, however irrational this could appear, to refer to ‘Empty orbitals.’ The characteristics of unoccupied orbitals are the same as those computed for electrons within them.

2. What is perhaps the greatest number of orbitals possible?

Ans. The values n=3 & l=1 indicate that it has been a 3p-orbital, however, the number \(f(m_{l}=0)\) indicates that it is indeed a \(3p_{z}\) in origin. As a result, the specified quantum number can only identify one orbital, namely 3p_z.

3. How do electrons fill orbitals?

Ans. According to the Aufbau principle, electrons first occupy lower-energy atomic orbitals before moving onto the higher ones. Based on this method, we may forecast the electronic structure of atoms and ions.