Atomic Number & Mass Number

Introduction

While the number of protons is merely the atomic number, the atomic mass of an atom is the sum of both its protons and neutrons. The letters A and Z can be used to denote these. Since it offers the key to the element’s existence, the atomic number is the concept that deals with such a periodic table element. It is only after interacting with this particular proton, which is primarily referred to as this hydrogen isotope’s protium, that the atomic and mass numbers are the same. Keep in mind, in particular, that while the atomic number remains constant, the mass number could change due to the presence of multiple isotopes. The elements are arranged in numerical order by atomic number.

image of Representation of an Atom with mass number and atomic number

Define Atomic Number

The number of protons in the nucleus of an atom is the atomic number. This is denoted by the letter Z. The number of electrons that surround the nuclei is controlled by the number of protons. In a periodic table with ascending atomic numbers, compounds with similar chemical properties typically cluster in the same column. Different elements have distinctive atomic numbers. For example, all C atoms have an atomic number of sixes, whereas all O atoms have an atomic number of eights.

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Define Mass Number

Rutherford proved that an atom’s nucleus, which is composed of protons and neutrons, contains perhaps the majority of the atom’s mass. The mass number refers to the total number of protons and neutrons in such an atom. Atomic mass units are used to measure this. To represent it, the letter “A” is frequently used. This has typically been accomplished by simultaneously adding both neutrons and protons.

For instance,\(Cl^{37}_{17} \) appears to have a mass number of 37. Its nucleus contains twenty neutrons and seventeen protons.

What is the difference between Valency, Atomic number and Mass number

ValencyAtomic NumberMass Number
The greatest amount of electrons that even an atom could lose, gain, as well as share, in addition to getting stable is referred to as valency.An atomic no. is the no. of protons that exist in such an atom.The mass no. within an atom is the total of its protons as well as neutrons.
The electronic arrangement of such an atom could be used to evaluate its valency.The mass number has always been less than the atomic no.The atomic no. is always greater than that of the mass number.
The no. of atoms does not affect valency.No. of neutrons in an atom does not impact its atomic no.The no. of neutrons inside an atom seems to not affect the mass no.
The no. of electrons does have a direct relationship with valency.The atomic no. of isotopes seems to be the same.The mass number of isotopes varies.
Elements are classified as monovalence, divalence, and trivalence based on their valency.Isobars with similar atomic no. cannot exist.The mass no. of isobars would be the same.

Energy Levels of Atomic Orbital

When an electron reaches a certain energy level, it is more likely to be found in these regions than in other regions. Orbitals are the name for those sections. Orbitals with roughly similar energies have created sub-levels. The maximum capacity for each orbital is two electrons. The energy of such an electron in a specific atom may be determined solely by the primary quantum number. In order of increasing orbital energy are the following orbitals:

\(1s<2s=2p<3s=3p=3d<4s=4p=4d=4f\)

Summary

The mass number of an atom’s nucleus is an integer equal to the sum of the nucleus’ protons and neutrons. The atomic number, in contrast, is simply the number of protons. Even though their mass is so small compared to that of protons and neutrons, electrons are not counted when calculating mass because they have no impact on the value. The number of neutrons may change, even though the number of protons in such an element’s units remains constant. An electron appears to have very little mass. Therefore, an atom’s atomic mass is roughly equivalent to its mass no. The mass number represents the weight of an atom’s nucleus in atomic mass units.

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Frequently Asked Questions (FAQs)

1. Is there a relationship between atomic mass and weight?

Ans: No, atomic mass is indeed the weight of an atom, while atomic weight denotes the weighted average of naturally produced elements.

2. Why does an atomic number refer to as a fingerprint?

Ans: The physical or chemical characteristics of an atom have been exclusively governed by the no. of electrons inside its nucleus, but often along with its nuclear charge: the nuclear charge would be an element’s specific “fingerprint,” as well as Z identifies the chemical components individually.

3. Why is it that a mass number is typically a whole number?

Ans: Since it is the total number of the particles, the mass no. is always a whole number. This varies from the atomic mass unit, which is well recognized, as well as written to 6 decimal points.

Electron Configuration

Introduction

The electronic configuration describes the distribution of electrons within an atomic subshell. An electron configuration is a summary of the prediction of the position of the electrons surrounding a nucleus. In every neutral atom, the electron number is the same as the proton number. Now we’ll arrange those electrons so that they form a ring around the nucleus, displaying their energy and the orbital type in which they are located. Electrons occupy orbitals in a specific order based on their energy.

What do you understand by Electron Configuration?

  • The electronic configuration describes the distribution of electrons within an atomic subshell.
  • Atomic electronic configurations follow a standard format in which each atomic subshell containing an electron is listed in ascending order.
  • For high atomic numbers, the standard representation of electronic configuration can be quite lengthy. In some cases, an abbreviated/condensed symbol may be used instead of the standard representation.
  • The electron configuration of Na, for example, is \(1{s^2}2{s^2}2{p^6}3{s^1}\).

How Subshells are important for Electron Configuration?

  • The azimuthal quantum no., represented by the letter “l,” determines the distribution of electrons into subshells.
  • The magnitude of the principal quantum no., n, dictates the magnitude of this quantum number. As a result, when n equals 4, four distinct subshells can exist.
  • For n = 4, the s, p, d, and f subshells correspond to l=0, 1, 2, 3 quantities.
  • Equation 2(2l+1) gives the maximum number of electrons that a subshell can hold.
  • The s, p, d, and f subshells can hold a maximum of 2, 6, 10, and 14 electrons, respectively.

Atomic Electronic Configuration Representation

This section provides examples of a few elements’ electronic configurations.

  • The electron configuration of hydrogen has an atomic number of one. As a result, an H atom has one electron, which will be assigned to the subshell of the first shell/s orbit. \(1{s^1}\) is the electronic configuration of H.Atomic structure of hydrogen.
  • The electron configuration of chlorine

Cl has the atomic number 17. As a result, its 17 electrons are distributed as follows:

The K has two electrons.

The L has 8 electrons and the M has 7 electrons.

The atomic structure of chlorine is shown in this image.

The electron configuration of Cl is depicted below. It is written as \(1{s^2}2{s^2}2{p^6}3{s^2}3{p^5}\).

Filling Atomic Orbitals

The following concepts govern how electrons are occupied in atomic orbitals.

Aufbau Principle

“The energy of an atomic orbital is calculated by adding the principal and azimuthal quantum numbers, and according to the Aufbau principle, electrons begin in relatively low energy orbitals and progress to higher energy orbitals.”

Pauli Exclusion Principle

“Only electron pairs with opposite spins can be carried in an atomic orbital, and no two electrons in the same atom have the same values for all four quantum numbers. If two electrons have the same principle, azimuthal, and magnetic numbers, they should have opposing spins.”

Hund’s Law

“Before a second electron is placed in an orbital, each orbital in a specific subshell is said to be entirely filled by electrons.”

Summary

It can be concluded that Electron configuration is the depiction of electron distribution inside an element’s atomic shells. Because the electrons are mathematically positioned in these subshells, the configuration aids in determining their position. The periodic table categorises elements based on their electron configurations. These make up the s, p, d, and f-block elements. The maximum number of electrons that can fit in a shell is determined by the principal quantum number (n). The azimuthal quantum number, represented by the letter “l,” governs the distribution of electrons into subshells.

Frequently Asked Questions

1. Why are specific electron configurations required for elements?
Ans. Electron configurations can shed light on an atom’s chemical behaviour by identifying its valence electrons. It also aids in the organisation of elements into different blocks such as s, p, d, and f blocks.

2. Describe the significance of electron configuration.
Ans. The significance is as follows:

They aid in determining the reactivity state of an atom.

It aids in the identification of both chemical and physical properties.

It foretells an atom’s magnetic properties.

3. For n=3, which subshells are present?
Ans. Each orbital can hold a maximum of two electrons, and there are four subshells present- s, p, d, and f for n=3. The maximum number of orbitals corresponding to the s, p, d, and f subshells is 1,3,5, and 7.

Formula Unit Mass

Introduction

The mass of the molecule that may be calculated from the molecular formula is the molecular mass unit. The chemical formula of the molecule’s mass, which indicates the number of atoms in the molecule, is known as the formula unit mass. The formula mass of the chemical formula is calculated using the atomic mass of the element. The formula mass unit is typically used to formulate the mass of ionic compounds, which are compounds made up of ions. It can be challenging to weigh small objects like atoms and molecules that are undetectable to the human eye. However, we have since created mass spectroscopy, which is used to determine the mass of atoms and molecules.

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Definition of formula mass

The mass of the chemical compound present is measured in terms of its formula mass unit. The number of moles of the atom present in the compound can be added to determine the formula mass unit. A unit of amu similar to the molecular mass unit exists in the formula mass unit. The molecular mass unit’s calculated mass can be the same as or different from the formula mass unit’s calculated mass. The attraction between molecules has no impact on the mass unit in the formula mass. The empirical formula of the compound determines the formula mass unit.

Unit of formula mass

The Atomic mass unit (amu) or um is the unit used in the formula mass unit (unified mass). The atomic mass unit can be defined as the mass of the twelfth part of the Carbon having atomic mass 12. 

Since hydrogen has an atomic mass of one, it was once used as a standard to determine the mass of other multielectron atoms. Due to the abundance of carbon atoms in the environment, however, the carbon atom with atomic mass 12 is usually used to refer to atomic mass.

Formula mass unit of ionic compounds

Formula mass units can be formulated by the addition of the mass of the number of moles of the atom present in the compound. The formula mass unit is based upon the empirical formula of the compound. By adding the mass of the number of moles of the atom present in the compound, formula mass units can be calculated. By adding the mass of the number of moles of the atom present in the compound, the molecular mass units can be calculated the empirical formula of the chemical serves as the base for the mass unit formula.

A huge number of both positively and negatively charged ions are linked together to form an ionic compound. For example, Magnesium oxide is an ionic compound made up of many Magnesium ions \(M{g^{2 + }}\), and Oxygen ions, \({O^{2 – }}\).

The formula unit of Magnesium oxide is MgO (which consists of one Mg2+, ion and Oxygen ion, O2-.ion)

For example,

1. Find out the formula mass unit of the ionic compound, such as potassium carbonate \({{\bf{K}}_{\bf{2}}}{\bf{C}}{{\bf{O}}_{\bf{3}}}\).

The formula mass of \({K_2}C{O_3}\) = Mass of 2 potassium atoms + Mass of one Carbon atom + Mass of 3 Oxygen atoms

=2 39+12+3 × 16

=78+12 +48

= 138 u

Thus, the formula mass of potassium carbonate is 138 u.

2. Calculate the formula unit mass of \({\bf{Ca}}{({\bf{OH}})_{\bf{2}}}\).


The Formula mass of \(Ca{\left( {OH} \right)_2}\), = mass of calcium atom + 2 (mass of oxygen atom+mass of the hydrogen atom)

= 40+2(16+1) 

= 74 u

The formula unit mass of Calcium Hydroxide is 74 u.

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Practical Applications of Formula Unit Mass

Stoichiometry and balanced equations

Stoichiometry and balanced equations Formula unit mass is essential for solving stoichiometry problems, allowing chemists to convert between the mass of a substance and the number of formula units. Understanding formula unit mass helps balance chemical equations and predict the amount of products formed or reactants consumed.

Determining empirical formulas

Determining empirical formulas Empirical formulas represent the simplest whole-number ratio of elements in a compound. By calculating the formula unit mass and using the mass percentages of each element, chemists can determine the empirical formula of a compound, which is crucial for understanding its chemical properties.

Calculating percent composition

Calculating percent composition Percent composition expresses the percentage of each element in a compound by mass. Using the formula unit mass and the atomic masses of the constituent elements, chemists can calculate the mass percentage of each element in a compound, allowing for deeper analysis and comparison of substances.

Analyzing chemical reactions and compounds

Analyzing chemical reactions and compounds Understanding formula unit mass enables chemists to explore the properties of ionic compounds and their reactions. Knowledge of formula unit mass assists in predicting reaction outcomes, determining limiting reactants, and identifying unknown compounds in analytical chemistry.

Summary

The term “formula unit” refers to the simplest possible ion arrangement that results in an electrically neutral unit in an ionic compound. Atomic mass units serve as the basis for the formula mass unit. The formula mass unit is the mass of the completed chemical formula, whereas the molecular mass unit is the mass of the molecular mass. By adding the atomic mass of the number of moles of the atom present in the formula, the formula unit mass may be calculated.

Frequently Asked Questions

1. What do you mean when you refer to an atomic mass unit?

Ans. A unit of atomic mass is defined as the mass of 12 parts of carbon, which has an atomic mass of 12. The abbreviation for the atomic mass unit is amu or um (unit mass).

2. What is the difference between molecular mass and formula mass of elements?

Ans. The molecular mass unit depends on the attractive force such as that which forms dimers or trimers, whereas the formula mass depends on the number of moles of atoms involved and not on the attractive force involved in forming dimers or trimers.

3. What is the formula unit mass? Give example.

Ans. The total atomic masses of the constituent elements of a compound are used to define the formula mass of a substance. This is typically applied to compounds that are made up of ions rather than separate molecules. For example, Sodium and chlorine ions are used to form NaCl (sodium chloride).

The formula mass of NaCl= Mass of 1 Sodium atom+ Mass of one Chlorine atom

=1 × 23+1 × 35.5

= 58.5 amu

Thus, the formula mass of NaCl is 58.5 amu